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TAGM 4046 Table 1 - Volatile Organic Contaminants

Table 1
Recommended soil cleanup objectives (mg/kg or ppm)
Volatile Organic Contaminants
Contaminant Partition
Coefficient,
Koc
Groundwater
Standards/
Criteria, Cw
(ug/l or ppb)
a
Allowable
soil conc.,
Cs (ppm)
b **
Soil cleanup
objectives
to protect
GW quality
(ppm)
USEPA Health Based (ppm) CRQL
(ppb)
***
Rec. Soil
Cleanup
Objective
(ppm)
Carcin-
ogens
Systemic
Toxicants
Acetone 2.2 50 0.0011 0.11 N/A 8,000 10 0.2
Benzene 83 0.7 0.0006 0.06 24 N/A 5 0.06
Benzoic Acid 54 * 50 0.027 2.7 N/A 300,000 5 2.7
2-Butanone 4.5 * 50 0.003 0.3 N/A 4,000 10 0.3
Carbon Disulfide 54 * 50 0.027 2.7 N/A 8,000 5 2.7
Carbon Tetrachloride 110 * 5 0.006 0.6 5.4 60 5 0.6
Chlorobenzene 330 5 0.017 1.7 N/A 2,000 5 1.7
Chloroethane 37 * 50 0.019 1.9 N/A N/A 10 1.9
Chloroform 31 7 0.003 0.30 114 800 5 0.3
Dibromochloromethane N/A 50 N/A N/A N/A N/A 5 N/A
1,2-Dichlorobenzene 1,700 4.7 0.079 7.9 N/A N/A 330 7.9
1,3-Dichlorobenzene 310 * 5 0.0155 1.55 N/A N/A 330 1.6
1,4-Dichlorobenzene 1,700 5 0.085 8.5 N/A N/A 330 8.5
1,1-Dichloroethane 30 5 0.002 0.2 N/A N/A 5 0.2
1,2-Dichloroethane 14 5 0.001 0.1 7.7 N/A 5 0.1
1,1-Dichloroethene 65 5 0.004 0.4 12 700 5 0.4
1,2-Dichloroethene (trans) 59 5 0.003 0.3 N/A 2,000 5 0.3
1-3 dichloropropane 51 5 0.003 0.3 N/A N/A 5 0.3
Ethylbenzene 1,100 5 0.055 5.5 N/A 8,000 5 5.5
113 Freon (1,1,2 Trichloro-
1,2,2 Trifluoroethane)
1,230 * 5 0.060 6.0 N/A 200,000 5 6.0
Methylene chloride 21 5 0.001 0.1 93 5,000 5 0.1
4-Methyl-2-Pentanone 19 * 50 0.01 1.0 N/A N/A 10 1.0
Tetrachloroethene 277 5 0.014 1.4 14 800 5 1.4
1,1,1-Trichloroethane 152 5 0.0076 0.76 N/A 7,000 5 0.8
1,1,2,2-Tetrachloroethane 118 5 0.006 0.6 35 N/A 5 0.6
1,2,3-trichloropropane 68 5 0.0034 0.34 N/A 80 5 0.4
1,2,4-trichlorobenzene 670 * 5 0.034 3.4 N/A N/A 330 3.4
Toluene 300 5 0.015 1.5 N/A 20,000 5 1.5
Trichloroethene 126 5 0.007 0.70 64 N/A 5 0.7
Vinyl chloride 57 2 0.0012 0.12 N/A N/A 10 0.2
Xylenes 240 5 0.012 1.2 N/A 200,000 -- 1.2

a. Allowable Soil Concentration Cs = f x Cw x Koc

b. Soil cleanup objective = Cs x Correction Factor (CF)

N/A is not available

* Partition coefficient is calculated by using the following equation:

log Koc = -0.55 log S + 3.64, where S is solubility in water in ppm.

All other Koc values are experimental values.

** Correction Factor (CF) of 100 is used as per TAGM #4046

*** As per TAGM #4046, Total VOCs < 10 ppm.

Note: Soil cleanup objectives are developed for soil organic carbon content (f) of 1%, and should be adjusted for the actual soil organic carbon content if it is known.